Two important laws were discovered during the 19th century relating to light and temperature:
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Here l is the wavelength in nanometers and T is the temperature in Kelvin (K).
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Here L is total energy emitted by a glowing body per unit area. T is the temperature and s is a constant. For a star with a radius R, the total radiating surface is given by 4pR2, so
,
where L is now the luminosity of the. If L and T are known, then the radius of the star can be determined by:

The website Online Journey Through Astronomy sponsored by Brooks/Cole Learning Center has a nice illustration of Wien’s Law and the Stefan-Boltzman. Law. Click on: Black Body Radiation Exercises
Knowing that color means temperature, stars can be sorted into broad categories. In 1866 father Peitro Angelo Secchi sorted stars into four broad categories and noted that the spectral lines correlated with color. His categories were:
· White – absorption lines mostly hydrogen
· Yellow (sun – like) – strong calcium lines, weaker hydrogen
· Red (Betelgeuse) – many bunched bands , few hydrogen lines
· Deep read (dim dwarf stars) – again, numerous bunched lines
In the late 1870s E.C. Pickering at Harvard began an all-out effort to obtain photographic spectra from thousands of stars. For this project, he employed an objective prism, a large prism “filter” fitted on the front end of a refracting telescope. With this device, all stars images projected onto the photographic plate are spread into spectra, and hundreds of stars can be cataloged and classified from one exposure. Pickering further subdivided Secchi’s categories:
· White – A,B,C,D
· Yellow – E,F,G,H,I,J,K,L
· Red – M
· Deep Red – N
Pickering noted that with this classification, the spectra went from strong hydrogen lines (stars like Sirius) to very weak hydrogen lines (stars like Betelgeuse). Although generally the weakening of H lines meant a steady march to the red (cool) end of the spectrum, there was a group of stars that showed virtually no lines at all but were blue-violet in color (therefore very hot). These stars were assigned the classification “O”.
By the end of the 19th century thousands of photographic plates, each with hundreds of stellar spectrograms, had been produced at Harvard Observatory. Most of the actual work of classifying these spectra was done by a group of women supervised by Annie Jump Cannon. In all Cannon and her group classified over a quarter million stars! Cannon noted that when the stars were arranged strictly by temperature, the spectral lines showed an increasing complexity as you went from hot to cool stars. In her view, hydrogen lines were not that important – it was the increase in the complexity that mattered. The explanation for this particular relation between spectral lines and the temperature had to wait for further clarification provided by atomic theory in the twentieth century.
However, with in a few years, it became the custom to arrange the spectral classes in the sequence suggested by Cannon – by temperature.
One consequence of the new arrangement was that those O stars which were very hot, but showed very faint lines had to be moved to the top of the list, and the B stars which had hydrogen lines, but were hotter than A stars had to be next. The sequence was further refined by combining some categories, effectively reducing the number of main classes to seven. Thus we arrive at the spectral sequence as we know it today:
The sequence is immortalized by the mnemonic devised by Pickering himself to memorize it:
Oh Be A Fine Girl/Guy Kiss Me
Other mnemonics include:
Oh Boy, An F Grade Kills Me
Overseas Bulletin - A Flash: Godzilla Kills Mothra
In some systems certain red stars are subdivided into classes R, N and S. The sequence OBAFGKMRNS lends itself to even more creative flights of fancy:
Oh Be A Fine Girl/Guy Kiss Me - Right Now Smack!
Oh Bring A Full Grown Kangaroo, My Recipe Needs Some
Oh Brutal And Fierce Gorilla, Kill My Roommate Next Saturday
On Bad Afternoons, Fermented Grapes Keep Mrs. Richard Nixon Smiling
There is an excellent website sponsored by the Wilderness Center of Wilnot, Ohio illustrating the spectral classes. Click on: Spectral Classes
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Where c is the speed of light. William Huggins in 1868 showed that it was possible to measure the line-of-sight velocity of a star (the radial velocity) using the Doppler technique.